Abstract

Ho³⁺/Yb³⁺: BaMoO₄ phosphors with different concentrations were fabricated by a gel combustion method. The upconversion (UC) luminescence, intrinsic optical bistability, and the corresponding mechanisms were reported for the present system. The optical thermometric properties based on red (⁵F₅→⁵I₈) and green (⁵F₄/⁵S₂→⁵I₈) emissions were studied. The sensing sensitivities could be tuned by manipulating the cooperative energy transfer process. The highest absolute sensitivity was 99 × 10⁻⁴ K⁻¹ at 573 K, which is larger than that of many previous UC materials.

© 2019 Chinese Laser Press

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