Polarization effect on the two-photon absorption of a chiral compound

M. G. Vivas; L. De Boni; Y. Bretonniere; C. Andraud; C. R. Mendonca

doi:10.1364/OE.20.018600

Polarization effect on the two-photon absorption of a chiral compound

M. G. Vivas, L. De Boni, Y. Bretonniere, C. Andraud, and C. R. Mendonca

Optics Express
Vol. 20,
Issue 17,
pp. 18600-18608
(2012)
•https://doi.org/10.1364/OE.20.018600

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M. G. Vivas, L. De Boni, Y. Bretonniere, C. Andraud, and C. R. Mendonca, "Polarization effect on the two-photon absorption of a chiral compound," Opt. Express 20, 18600-18608 (2012)

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Related Topics
Table of Contents Category
- Nonlinear Optics
Optics & Photonics Topics
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The topics in this list come from the OSA Optics and Photonics Topics applied to this article.
Previously assigned OCIS codes
- Multiphoton processes (190.4180)
- Optical nonlinearities in organic materials (190.4710)

About this Article
History
- Original Manuscript: June 15, 2012
- Revised Manuscript: July 22, 2012
- Manuscript Accepted: July 22, 2012
- Published: July 30, 2012

Accessible

Open Access

Abstract

In this report, we investigate the polarization effect (linear, elliptical and circular) on the two-photon absorption (2PA) properties of a chiral compound based in azoaromatic moieties using the femtosecond Z-scan technique with low repetition rate and low pulse energy. We observed a strong 2PA modulation between 800 nm and 960 nm as a function the polarization changes from linear through elliptical to circular. Such results were interpreted employing the sum-over-essential states approach, which allowed us to model the 2PA circular-linear dichroism effect and to identifier the overlapping of the excited electronic states responsible by the 2PA allowed band.

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References

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J. W. Perry, B. H. Cumpston, S. P. Ananthavel, S. Barlow, D. L. Dyer, J. E. Ehrlich, L. L. Erskine, A. A. Heikal, S. M. Kuebler, I.-Y. S. Lee, D. McCord-Maughon, J. Qin, H. Röckel, M. Rumi, X.-L. Wu, and S. R. Marder, “Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication,” Nature 398(6722), 51–54 (1999).
[Crossref]
P. H. D. Ferreira, M. G. Vivas, D. L. Silva, L. Misoguti, K. Feng, X. R. Bu, and C. R. Mendonca, “Nonlinear spectrum effect on the coherent control of molecular systems,” Opt. Commun. 284(13), 3433–3436 (2011).
[Crossref]
D. Gindre, A. Boeglin, A. Fort, L. Mager, and K. D. Dorkenoo, “Rewritable optical data storage in azobenzene copolymers,” Opt. Express 14(21), 9896–9901 (2006).
[Crossref] [PubMed]
J. M. Hales, J. Matichak, S. Barlow, S. Ohira, K. Yesudas, J. L. Brédas, J. W. Perry, and S. R. Marder, “Design of polymethine dyes with large third-order optical nonlinearities and loss figures of merit,” Science 327(5972), 1485–1488 (2010).
[Crossref] [PubMed]
A. Ovsianikov, X. Shizhou, M. Farsari, M. Vamvakaki, C. Fotakis, and B. N. Chichkov, “Shrinkage of microstructures produced by two-photon polymerization of Zr-based hybrid photosensitive materials,” Opt. Express 17(4), 2143–2148 (2009).
[Crossref] [PubMed]
S. Brasselet, V. Le Floc’h, F. Treussart, J.-F. Roch, J. Zyss, E. Botzung-Appert, and A. Ibanez, “In situ diagnostics of the crystalline nature of single organic nanocrystals by nonlinear microscopy,” Phys. Rev. Lett. 92(20), 207401 (2004).
[Crossref] [PubMed]
S. Brasselet and J. Zyss, “Nonlinear polarimetry of molecular crystals down to the nanoscale,” C. R. Phys. 8(2), 165–179 (2007).
[Crossref]
C. Toro, L. De Boni, N. Lin, F. Santoro, A. Rizzo, and F. E. Hernandez, “Two-photon absorption circular dichroism: a new twist in nonlinear spectroscopy,” Chemistry 16(11), 3504–3509 (2010).
[Crossref] [PubMed]
C. Toro, L. De Boni, N. Lin, F. Santoro, A. Rizzo, and F. E. Hernandez, “Two-photon absorption circular-linear dichroism on axial enantiomers,” Chirality 22(1ESuppl 1), E202–E210 (2010).
[Crossref] [PubMed]
W. J. Meath and E. A. Power, “On the importance of permanent moments in multiphoton absorption using perturbation theory,” J. Phys. B. 17(5), 763–781 (1984).
[Crossref]
M. A. C. Nascimento, “The polarization dependence of 2-photon absorption rates for randomly oriented molecules,” Chem. Phys. 74(1), 51–66 (1983).
[Crossref]
E. A. Power, “Two-photon circular dichroism,” J. Chem. Phys. 63(4), 1348–1350 (1975).
[Crossref]
I. Tinoco, “Two-photon circular dichroism,” J. Chem. Phys. 62(3), 1006–1009 (1975).
[Crossref]
J. Lazar, A. Bondar, S. Timr, and S. J. Firestein, “Two-photon polarization microscopy reveals protein structure and function,” Nat. Methods 8(8), 684–690 (2011).
[Crossref] [PubMed]
J. Olesiak-Banska, H. Mojzisova, D. Chauvat, M. Zielinski, K. Matczyszyn, P. Tauc, and J. Zyss, “Liquid crystal phases of DNA: evaluation of DNA organization by two-photon fluorescence microscopy and polarization analysis,” Biopolymers 95(6), 365–375 (2011).
[Crossref] [PubMed]
H. Mojzisova, J. Olesiak, M. Zielinski, K. Matczyszyn, D. Chauvat, and J. Zyss, “Polarization-sensitive two-photon microscopy study of the organization of liquid-crystalline DNA,” Biophys. J. 97(8), 2348–2357 (2009).
[Crossref] [PubMed]
L. De Boni, C. Toro, and F. E. Hernández, “Synchronized double L-scan technique for the simultaneous measurement of polarization-dependent two-photon absorption in chiral molecules,” Opt. Lett. 33(24), 2958–2960 (2008).
[Crossref] [PubMed]
P. P. Markowicz, M. Samoca, J. Cerne, P. N. Prasad, A. Pucci, and G. Ruggeri, “Modified Z-scan techniques for investigations of nonlinear chiroptical effects,” Opt. Express 12(21), 5209–5214 (2004).
[Crossref] [PubMed]
C. Diaz, N. Lin, C. Toro, R. Passier, A. Rizzo, and F. E. Hernández, “The Effect of the π-Electron Delocalization Curvature on the Two-Photon Circular Dichroism of Molecules with Axial Chirality,” J. Phys. Chem. Lett. 3(13), 1808–1813 (2012).
[Crossref]
A. Nag and D. Goswami, “Polarization induced control of single and two-photon fluorescence,” J. Chem. Phys. 132(15), 154508 (2010).
[Crossref] [PubMed]
Y. Zeng, C. Wang, F. Zhao, X. Huang, and Y. Cheng, “Polarization-induced control of two-photon excited fluorescence in a chiral polybinaphthyl,” Opt. Lett. 36, 2982–2984 (2011).
M. G. Vivas, D. L. Silva, L. De Boni, Y. Bretonniere, C. Andraud, F. Laibe-Darbour, J.-C. Mulatier, R. Zaleśny, W. Bartkowiak, S. Canuto, and C. R. Mendonca, are preparing a manuscript to be called “Experimental and theoretical study on the one- and two-photon absorption properties of a novel class of phenylacetylene and azoaromatic compounds”.
D. Wanapun, R. D. Wampler, N. J. Begue, and G. J. Simpson, “Polarization-dependent two-photon absorption for the determination of protein secondary structure: A theoretical study,” Chem. Phys. Lett. 455(1-3), 6–12 (2008).
[Crossref]
K. D. Bonin and T. J. McIlrath, “Two-photon electric-dipole selection rules,” J. Opt. Soc. Am. B 1(1), 52–55 (1984).
[Crossref]
M. Drobizhev, F. Meng, A. Rebane, Y. Stepanenko, E. Nickel, and C. W. Spangler, “Strong two-photon absorption in new asymmetrically substituted porphyrins: interference between charge-transfer and intermediate-resonance pathways,” J. Phys. Chem. B 110(20), 9802–9814 (2006).
[Crossref] [PubMed]
M. G. Vivas, S. L. Nogueira, H. S. Silva, N. M. Barbosa Neto, A. Marletta, F. Serein-Spirau, S. Lois, T. Jarrosson, L. De Boni, R. A. Silva, and C. R. Mendonca, “Linear and nonlinear optical properties of the thiophene/phenylene-based oligomer and polymer,” J. Phys. Chem. B 115(44), 12687–12693 (2011).
[Crossref] [PubMed]
L. Onsager, “Electric moments of molecules in liquids,” J. Am. Chem. Soc. 58(8), 1486–1493 (1936).
[Crossref]
M. G. Vivas, E. Piovesan, D. L. Silva, T. M. Cooper, L. De Boni, and C. R. Mendonca, “Broadband three-photon absorption spectra of platinum acetylide complexes,” Opt. Mater. Express 1(4), 700–710 (2011).
[Crossref]
K. Ohta, L. Antonov, S. Yamada, and K. Kamada, “Theoretical study of the two-photon absorption properties of several asymmetrically substituted stilbenoid molecules,” J. Chem. Phys. 127(8), 084504 (2007).
[Crossref] [PubMed]
K. Kamada, K. Ohta, Y. Iwase, and K. Kondo, “Two-photon absorption properties of symmetric substituted diacetylene: drastic enhancement of the cross section near the one-photon absorption peak,” Chem. Phys. Lett. 372(3-4), 386–393 (2003).
[Crossref]

2012 (1)

C. Diaz, N. Lin, C. Toro, R. Passier, A. Rizzo, and F. E. Hernández, “The Effect of the π-Electron Delocalization Curvature on the Two-Photon Circular Dichroism of Molecules with Axial Chirality,” J. Phys. Chem. Lett. 3(13), 1808–1813 (2012).
[Crossref]

2011 (6)

J. Lazar, A. Bondar, S. Timr, and S. J. Firestein, “Two-photon polarization microscopy reveals protein structure and function,” Nat. Methods 8(8), 684–690 (2011).
[Crossref] [PubMed]

J. Olesiak-Banska, H. Mojzisova, D. Chauvat, M. Zielinski, K. Matczyszyn, P. Tauc, and J. Zyss, “Liquid crystal phases of DNA: evaluation of DNA organization by two-photon fluorescence microscopy and polarization analysis,” Biopolymers 95(6), 365–375 (2011).
[Crossref] [PubMed]

P. H. D. Ferreira, M. G. Vivas, D. L. Silva, L. Misoguti, K. Feng, X. R. Bu, and C. R. Mendonca, “Nonlinear spectrum effect on the coherent control of molecular systems,” Opt. Commun. 284(13), 3433–3436 (2011).
[Crossref]

Y. Zeng, C. Wang, F. Zhao, X. Huang, and Y. Cheng, “Polarization-induced control of two-photon excited fluorescence in a chiral polybinaphthyl,” Opt. Lett. 36, 2982–2984 (2011).

M. G. Vivas, S. L. Nogueira, H. S. Silva, N. M. Barbosa Neto, A. Marletta, F. Serein-Spirau, S. Lois, T. Jarrosson, L. De Boni, R. A. Silva, and C. R. Mendonca, “Linear and nonlinear optical properties of the thiophene/phenylene-based oligomer and polymer,” J. Phys. Chem. B 115(44), 12687–12693 (2011).
[Crossref] [PubMed]

M. G. Vivas, E. Piovesan, D. L. Silva, T. M. Cooper, L. De Boni, and C. R. Mendonca, “Broadband three-photon absorption spectra of platinum acetylide complexes,” Opt. Mater. Express 1(4), 700–710 (2011).
[Crossref]

2010 (4)

J. M. Hales, J. Matichak, S. Barlow, S. Ohira, K. Yesudas, J. L. Brédas, J. W. Perry, and S. R. Marder, “Design of polymethine dyes with large third-order optical nonlinearities and loss figures of merit,” Science 327(5972), 1485–1488 (2010).
[Crossref] [PubMed]

C. Toro, L. De Boni, N. Lin, F. Santoro, A. Rizzo, and F. E. Hernandez, “Two-photon absorption circular dichroism: a new twist in nonlinear spectroscopy,” Chemistry 16(11), 3504–3509 (2010).
[Crossref] [PubMed]

C. Toro, L. De Boni, N. Lin, F. Santoro, A. Rizzo, and F. E. Hernandez, “Two-photon absorption circular-linear dichroism on axial enantiomers,” Chirality 22(1ESuppl 1), E202–E210 (2010).
[Crossref] [PubMed]

A. Nag and D. Goswami, “Polarization induced control of single and two-photon fluorescence,” J. Chem. Phys. 132(15), 154508 (2010).
[Crossref] [PubMed]

2009 (2)

H. Mojzisova, J. Olesiak, M. Zielinski, K. Matczyszyn, D. Chauvat, and J. Zyss, “Polarization-sensitive two-photon microscopy study of the organization of liquid-crystalline DNA,” Biophys. J. 97(8), 2348–2357 (2009).
[Crossref] [PubMed]

A. Ovsianikov, X. Shizhou, M. Farsari, M. Vamvakaki, C. Fotakis, and B. N. Chichkov, “Shrinkage of microstructures produced by two-photon polymerization of Zr-based hybrid photosensitive materials,” Opt. Express 17(4), 2143–2148 (2009).
[Crossref] [PubMed]

2008 (2)

L. De Boni, C. Toro, and F. E. Hernández, “Synchronized double L-scan technique for the simultaneous measurement of polarization-dependent two-photon absorption in chiral molecules,” Opt. Lett. 33(24), 2958–2960 (2008).
[Crossref] [PubMed]

D. Wanapun, R. D. Wampler, N. J. Begue, and G. J. Simpson, “Polarization-dependent two-photon absorption for the determination of protein secondary structure: A theoretical study,” Chem. Phys. Lett. 455(1-3), 6–12 (2008).
[Crossref]

2007 (2)

K. Ohta, L. Antonov, S. Yamada, and K. Kamada, “Theoretical study of the two-photon absorption properties of several asymmetrically substituted stilbenoid molecules,” J. Chem. Phys. 127(8), 084504 (2007).
[Crossref] [PubMed]

S. Brasselet and J. Zyss, “Nonlinear polarimetry of molecular crystals down to the nanoscale,” C. R. Phys. 8(2), 165–179 (2007).
[Crossref]

2006 (2)

D. Gindre, A. Boeglin, A. Fort, L. Mager, and K. D. Dorkenoo, “Rewritable optical data storage in azobenzene copolymers,” Opt. Express 14(21), 9896–9901 (2006).
[Crossref] [PubMed]

M. Drobizhev, F. Meng, A. Rebane, Y. Stepanenko, E. Nickel, and C. W. Spangler, “Strong two-photon absorption in new asymmetrically substituted porphyrins: interference between charge-transfer and intermediate-resonance pathways,” J. Phys. Chem. B 110(20), 9802–9814 (2006).
[Crossref] [PubMed]

2004 (2)

S. Brasselet, V. Le Floc’h, F. Treussart, J.-F. Roch, J. Zyss, E. Botzung-Appert, and A. Ibanez, “In situ diagnostics of the crystalline nature of single organic nanocrystals by nonlinear microscopy,” Phys. Rev. Lett. 92(20), 207401 (2004).
[Crossref] [PubMed]

P. P. Markowicz, M. Samoca, J. Cerne, P. N. Prasad, A. Pucci, and G. Ruggeri, “Modified Z-scan techniques for investigations of nonlinear chiroptical effects,” Opt. Express 12(21), 5209–5214 (2004).
[Crossref] [PubMed]

2003 (1)

K. Kamada, K. Ohta, Y. Iwase, and K. Kondo, “Two-photon absorption properties of symmetric substituted diacetylene: drastic enhancement of the cross section near the one-photon absorption peak,” Chem. Phys. Lett. 372(3-4), 386–393 (2003).
[Crossref]

1999 (1)

J. W. Perry, B. H. Cumpston, S. P. Ananthavel, S. Barlow, D. L. Dyer, J. E. Ehrlich, L. L. Erskine, A. A. Heikal, S. M. Kuebler, I.-Y. S. Lee, D. McCord-Maughon, J. Qin, H. Röckel, M. Rumi, X.-L. Wu, and S. R. Marder, “Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication,” Nature 398(6722), 51–54 (1999).
[Crossref]

1984 (2)

W. J. Meath and E. A. Power, “On the importance of permanent moments in multiphoton absorption using perturbation theory,” J. Phys. B. 17(5), 763–781 (1984).
[Crossref]

K. D. Bonin and T. J. McIlrath, “Two-photon electric-dipole selection rules,” J. Opt. Soc. Am. B 1(1), 52–55 (1984).
[Crossref]

1983 (1)

M. A. C. Nascimento, “The polarization dependence of 2-photon absorption rates for randomly oriented molecules,” Chem. Phys. 74(1), 51–66 (1983).
[Crossref]

1975 (2)

E. A. Power, “Two-photon circular dichroism,” J. Chem. Phys. 63(4), 1348–1350 (1975).
[Crossref]

I. Tinoco, “Two-photon circular dichroism,” J. Chem. Phys. 62(3), 1006–1009 (1975).
[Crossref]

1936 (1)

L. Onsager, “Electric moments of molecules in liquids,” J. Am. Chem. Soc. 58(8), 1486–1493 (1936).
[Crossref]

Ananthavel, S. P.

Antonov, L.

Barbosa Neto, N. M.

Barlow, S.

Begue, N. J.

Boeglin, A.

D. Gindre, A. Boeglin, A. Fort, L. Mager, and K. D. Dorkenoo, “Rewritable optical data storage in azobenzene copolymers,” Opt. Express 14(21), 9896–9901 (2006).
[Crossref] [PubMed]

Bondar, A.

J. Lazar, A. Bondar, S. Timr, and S. J. Firestein, “Two-photon polarization microscopy reveals protein structure and function,” Nat. Methods 8(8), 684–690 (2011).
[Crossref] [PubMed]

Bonin, K. D.

K. D. Bonin and T. J. McIlrath, “Two-photon electric-dipole selection rules,” J. Opt. Soc. Am. B 1(1), 52–55 (1984).
[Crossref]

Botzung-Appert, E.

Brasselet, S.

S. Brasselet and J. Zyss, “Nonlinear polarimetry of molecular crystals down to the nanoscale,” C. R. Phys. 8(2), 165–179 (2007).
[Crossref]

Brédas, J. L.

Bu, X. R.

Cerne, J.

Chauvat, D.

Cheng, Y.

Y. Zeng, C. Wang, F. Zhao, X. Huang, and Y. Cheng, “Polarization-induced control of two-photon excited fluorescence in a chiral polybinaphthyl,” Opt. Lett. 36, 2982–2984 (2011).

Chichkov, B. N.

Cooper, T. M.

Cumpston, B. H.

De Boni, L.

Diaz, C.

Dorkenoo, K. D.

D. Gindre, A. Boeglin, A. Fort, L. Mager, and K. D. Dorkenoo, “Rewritable optical data storage in azobenzene copolymers,” Opt. Express 14(21), 9896–9901 (2006).
[Crossref] [PubMed]

Drobizhev, M.

Dyer, D. L.

Ehrlich, J. E.

Erskine, L. L.

Farsari, M.

Feng, K.

Ferreira, P. H. D.

Firestein, S. J.

J. Lazar, A. Bondar, S. Timr, and S. J. Firestein, “Two-photon polarization microscopy reveals protein structure and function,” Nat. Methods 8(8), 684–690 (2011).
[Crossref] [PubMed]

Fort, A.

D. Gindre, A. Boeglin, A. Fort, L. Mager, and K. D. Dorkenoo, “Rewritable optical data storage in azobenzene copolymers,” Opt. Express 14(21), 9896–9901 (2006).
[Crossref] [PubMed]

Fotakis, C.

Gindre, D.

D. Gindre, A. Boeglin, A. Fort, L. Mager, and K. D. Dorkenoo, “Rewritable optical data storage in azobenzene copolymers,” Opt. Express 14(21), 9896–9901 (2006).
[Crossref] [PubMed]

Goswami, D.

A. Nag and D. Goswami, “Polarization induced control of single and two-photon fluorescence,” J. Chem. Phys. 132(15), 154508 (2010).
[Crossref] [PubMed]

Hales, J. M.

Heikal, A. A.

Hernandez, F. E.

Hernández, F. E.

Huang, X.

Y. Zeng, C. Wang, F. Zhao, X. Huang, and Y. Cheng, “Polarization-induced control of two-photon excited fluorescence in a chiral polybinaphthyl,” Opt. Lett. 36, 2982–2984 (2011).

Ibanez, A.

Iwase, Y.

Jarrosson, T.

Kamada, K.

Kondo, K.

Kuebler, S. M.

Lazar, J.

J. Lazar, A. Bondar, S. Timr, and S. J. Firestein, “Two-photon polarization microscopy reveals protein structure and function,” Nat. Methods 8(8), 684–690 (2011).
[Crossref] [PubMed]

Le Floc’h, V.

Lee, I.-Y. S.

Lin, N.

Lois, S.

Mager, L.

D. Gindre, A. Boeglin, A. Fort, L. Mager, and K. D. Dorkenoo, “Rewritable optical data storage in azobenzene copolymers,” Opt. Express 14(21), 9896–9901 (2006).
[Crossref] [PubMed]

Marder, S. R.

Markowicz, P. P.

Marletta, A.

Matczyszyn, K.

Matichak, J.

McCord-Maughon, D.

McIlrath, T. J.

K. D. Bonin and T. J. McIlrath, “Two-photon electric-dipole selection rules,” J. Opt. Soc. Am. B 1(1), 52–55 (1984).
[Crossref]

Meath, W. J.

W. J. Meath and E. A. Power, “On the importance of permanent moments in multiphoton absorption using perturbation theory,” J. Phys. B. 17(5), 763–781 (1984).
[Crossref]

Mendonca, C. R.

Meng, F.

Misoguti, L.

Mojzisova, H.

Nag, A.

A. Nag and D. Goswami, “Polarization induced control of single and two-photon fluorescence,” J. Chem. Phys. 132(15), 154508 (2010).
[Crossref] [PubMed]

Nascimento, M. A. C.

M. A. C. Nascimento, “The polarization dependence of 2-photon absorption rates for randomly oriented molecules,” Chem. Phys. 74(1), 51–66 (1983).
[Crossref]

Nickel, E.

Nogueira, S. L.

Ohira, S.

Ohta, K.

Olesiak, J.

Olesiak-Banska, J.

Onsager, L.

L. Onsager, “Electric moments of molecules in liquids,” J. Am. Chem. Soc. 58(8), 1486–1493 (1936).
[Crossref]

Ovsianikov, A.

Passier, R.

Perry, J. W.

Piovesan, E.

Power, E. A.

W. J. Meath and E. A. Power, “On the importance of permanent moments in multiphoton absorption using perturbation theory,” J. Phys. B. 17(5), 763–781 (1984).
[Crossref]

E. A. Power, “Two-photon circular dichroism,” J. Chem. Phys. 63(4), 1348–1350 (1975).
[Crossref]

Prasad, P. N.

Pucci, A.

Qin, J.

Rebane, A.

Rizzo, A.

Roch, J.-F.

Röckel, H.

Ruggeri, G.

Rumi, M.

Samoca, M.

Santoro, F.

Serein-Spirau, F.

Shizhou, X.

Silva, D. L.

Silva, H. S.

Silva, R. A.

Simpson, G. J.

Spangler, C. W.

Stepanenko, Y.

Tauc, P.

Timr, S.

J. Lazar, A. Bondar, S. Timr, and S. J. Firestein, “Two-photon polarization microscopy reveals protein structure and function,” Nat. Methods 8(8), 684–690 (2011).
[Crossref] [PubMed]

Tinoco, I.

I. Tinoco, “Two-photon circular dichroism,” J. Chem. Phys. 62(3), 1006–1009 (1975).
[Crossref]

Toro, C.

Treussart, F.

Vamvakaki, M.

Vivas, M. G.

Wampler, R. D.

Wanapun, D.

Wang, C.

Y. Zeng, C. Wang, F. Zhao, X. Huang, and Y. Cheng, “Polarization-induced control of two-photon excited fluorescence in a chiral polybinaphthyl,” Opt. Lett. 36, 2982–2984 (2011).

Wu, X.-L.

Yamada, S.

Yesudas, K.

Zeng, Y.

Y. Zeng, C. Wang, F. Zhao, X. Huang, and Y. Cheng, “Polarization-induced control of two-photon excited fluorescence in a chiral polybinaphthyl,” Opt. Lett. 36, 2982–2984 (2011).

Zhao, F.

Y. Zeng, C. Wang, F. Zhao, X. Huang, and Y. Cheng, “Polarization-induced control of two-photon excited fluorescence in a chiral polybinaphthyl,” Opt. Lett. 36, 2982–2984 (2011).

Zielinski, M.

Zyss, J.

S. Brasselet and J. Zyss, “Nonlinear polarimetry of molecular crystals down to the nanoscale,” C. R. Phys. 8(2), 165–179 (2007).
[Crossref]

Biophys. J. (1)

Biopolymers (1)

C. R. Phys. (1)

S. Brasselet and J. Zyss, “Nonlinear polarimetry of molecular crystals down to the nanoscale,” C. R. Phys. 8(2), 165–179 (2007).
[Crossref]

Chem. Phys. (1)

M. A. C. Nascimento, “The polarization dependence of 2-photon absorption rates for randomly oriented molecules,” Chem. Phys. 74(1), 51–66 (1983).
[Crossref]

Chem. Phys. Lett. (2)

Chemistry (1)

Chirality (1)

J. Am. Chem. Soc. (1)

L. Onsager, “Electric moments of molecules in liquids,” J. Am. Chem. Soc. 58(8), 1486–1493 (1936).
[Crossref]

J. Chem. Phys. (4)

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Fig. 1 Molecular structure of the chiral compound (YB3p25).

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Fig. 2 (a) Linear absorption spectrum of the YB3p25. (b) 2PA cross-section spectra with linearly (circles), right (squares) and left (up triangles) circularly polarized laser pulse and the solid line along it is the theoretical fitting obtained employing the sum-over-essential states approach.

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Fig. 3 Open-aperture Z-scan curves for YB3p25 with linearly (circles), left (up triangles) and right (squares) circularly polarized light. The solid line represents the fitting employing the Eq. (1).

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Fig. 4 (a) 2PA-CLD spectrum of the YB3p25 (diamonds). Solid and dashed lines represent the fit employing the Eq. (3) with and without the interference term, respectively. (b) Normalized transmittance change (log-log scale) as a function of laser irradiance showing the slope of approximately 1.0 for the LP and CP light beam. The inset shows the circular/linear 2PA ratio (

Ω_{C L D}

) as a function of irradiance.

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Fig. 5 2 + 3 energy-level diagram with

Δ {\vec{μ}}_{g e} \neq 0

used in sum-over-essential states approach in order to model the 2PA-CLD spectrum (solid lines). There are two distinct transition pathways for 2PA in this system. The first path involves the difference between permanent dipole moment of the first excited and ground states (red arrows) while the second involve a real intermediate resonance (blue arrows) due to the detuning between the photon energy and the first excited state allowed by 1PA. Hollow arrows show the transition dipole moments.

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Fig. 6 (a) Experimental (squares) 2PA cross-section modulation for YB3p25 at 880 nm. The solid curve is the fitting of the experimental data using Eq. (5) with

ε = 10^{\circ}

. (b) Simulations from Eq. (5) assuming distinct values for the angle between dipole moments (

ε

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Tables (1)

Table 1 Spectroscopic parameters used/obtained (highlight) in/from the sum-over-essential states approach adopting a 2 + 3 energy-level diagram, with $ν = ω / 2 π$ .

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Equations (5)

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T (z) = \frac{1}{\sqrt{π} q_{o} (z, 0)} \int_{- \infty}^{\infty} \ln [1 + q_{o} (z, 0) e^{- τ^{2}}] d τ

q_{o} = β I_{o} L {(1 + (z^{2} / z_{o}^{2}))}^{- 1},

σ_{g \to f}^{(2 P A)} (ω) = \frac{2}{30} \frac{{(2 π)}^{5}}{{(n h c)}^{2}} L^{4} {\begin{cases} P (ε_{_{Δ {\vec{μ}}_{g e} {\vec{μ}}_{g e}}}) {| {\vec{μ}}_{g e} |}^{2} {| Δ {\vec{μ}}_{g e} |}^{2} g_{e} (2 ω) + (D) \\ \frac{ω^{2}}{{(ω_{g e} - ω)}^{2} + Γ_{g e}^{2} (ω)} (P (ε_{_{{\vec{μ}}_{g e} {\vec{μ}}_{e f}}}) {| {\vec{μ}}_{g e} |}^{2} {| {\vec{μ}}_{e f} |}^{2}) g_{f} (2 ω) + (I R) \\ \frac{2 ω (ω_{g e} - ω)}{[{(ω_{g e} - ω)}^{2} + Γ_{g e}^{2} (ω)]} (P (\cos (ε)) {| {\vec{μ}}_{g e} |}^{2} | Δ {\vec{μ}}_{g e} | | {\vec{μ}}_{e f} |) g_{f} (2 ω) (Q I) \end{cases}} .

{| {\vec{μ}}_{g \to e, f} |}^{2} g_{e, f} = \frac{3 \times 10^{3} \ln (10) h c}{{(2 π)}^{2} N_{A}} \frac{n}{L^{2}} \frac{ξ_{e, f} (ω)}{ω}

σ_{2 P A} (ω) = σ_{2 P A}^{L P} (ω) [(1 - \frac{\cos^{2} (ε) + 3}{4 \cos^{2} (ε) + 2}) \cos^{2} (2 θ) + (\frac{\cos^{2} (ε) + 3}{4 \cos^{2} (ε) + 2})],

Parameters	YB3p25
ν_ge (eV)	2.70 (460 nm)
ν_gf (eV)	2.85 (435 nm)
Γ_ge (eV)	0.20 ± 0.02
Γ_gf (eV)	0.20 ± 0.02
μ_ge (Debye)	9.0 ± 1.0
μ_ef (Debye)	9.5 ± 2.0
∆μ_ge (Debye)	10.5 ± 2.0