Abstract

Eu3+-activated CdY4MoO16 nanoparticles were synthesized via the sol-gel method. The phase formations were confirmed by the structural refinements. The photoluminescence properties such as the excitation and emission spectra, optimal doping level, internal absolute quantum efficiency (QE), decay lifetimes and the thermal stability, were measured. The charge transfer band (CTB) has a dependence on the Eu3+-content, showing an obvious red-shift with the increase of doping levels. Especially, CTB could reach a longer wavelength than the reported Eu3+-doped molydates. Moreover, the phosphor has some priorities such as high quantum efficiency, high doping levels and good thermal stability, etc. The excellent luminescence of Eu3+-activated CdY4MoO16 was discussed on its structural characteristics such as the cubic fluorite-like crystalline phase, framework constructed by Mo-O polyhedral groups, and the positive charge deficiency in the Eu3+-occupied cation sites of (Cd0.5, Y0.5)2.5 in the lattices.

© 2016 Optical Society of America

Full Article  |  PDF Article

Corrections

Ruijin Yu, Aiping Fan, Maosen Yuan, Tianbao Li, Qin Tu, Jinyi Wang, and Vincent Rotello, "Eu3+-activated CdY4Mo3O16 nanoparticles with narrow red-emission and broad excitation in near-UV wavelength region: publisher’s note," Opt. Mater. Express 6, 3469-3469 (2016)
https://www.osapublishing.org/ome/abstract.cfm?uri=ome-6-11-3469

3 October 2016: Corrections were made to the author listing and the funding section.


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References

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  1. X. Y. Chen, Z. J. Zhang, F. F. Xu, S. Q. Shi, and J. T. Zhao, “Color-Tunable Carbon Dots/Y2WO6:Eu3+ Embedded Composite Bulk,” Opt. Mater. Express 6(2), 374–380 (2016).
    [Crossref]
  2. P. S. Dutta and A. Khanna, “Eu3+ Activated Molybdate and Tungstate Based Red Phosphors with Charge Transfer Band in Blue Region,” ECS J. Solid State Sci. Technol. 2(2), R3153–R3167 (2012).
    [Crossref]
  3. J. B. Bourdet, R. Chevalier, J. P. Fournier, R. Kohlmuller, and J. Omaly, “A Structural Study of Cadmium Yttrium Molybdate CdY4Mo3O16,” Acta Crystallogr. B 38(9), 2371–2374 (1982).
    [Crossref]
  4. A. R. Denton and N. W. Ashcroft, “Vegard’s Law,” Phys. Rev. A 43(6), 3161–3164 (1991).
    [Crossref] [PubMed]
  5. P. Dorenbos, A. H. Krumpel, E. Kolk, P. Boutinaud, M. Bettinelli, and E. Cavalli, “Lanthanide Level Location in Transition Metal Complex Compounds,” Opt. Mater. 32(12), 1681–1685 (2010).
    [Crossref]
  6. E. Cavalli, P. Boutinaud, R. Mahiou, M. Bettinelli, and P. Dorenbos, “Luminescence Dynamics in Tb3+-doped CaWO4 and CaMoO4 Crystals,” Inorg. Chem. 49(11), 4916–4921 (2010).
    [Crossref] [PubMed]
  7. Y. L. Yang, X. M. Li, W. L. Feng, W. J. Yang, W. L. Li, and C. Y. Tao, “Effect of Surfactants on Morphology and Luminescent Properties of CaMoO4:Eu3+ Red Phosphors,” J. Alloys Compd. 509(3), 845–848 (2011).
    [Crossref]
  8. F. Du, Y. Nakai, T. Tsuboi, Y. Huang, and H. J. Seo, “Luminescence Properties and Site Occupations of Eu3+ Ions Doped in Double phosphates Ca9R(PO4)7 (R = Al, Lu),” J. Mater. Chem. 21(12), 4669–4678 (2011).
    [Crossref]
  9. C. H. Huang, T. W. Kuo, and T. M. Chen, “Thermally stable green Ba(3)Y(PO(4))3:Ce(3+),Tb(3+) and red Ca(3)Y(AlO)(3)(BO(3))4:Eu(3+) phosphors for white-light fluorescent lamps,” Opt. Express 19(S1), A1–A6 (2011).
    [Crossref] [PubMed]
  10. L. Han, G. Liu, X. Dong, J. Wang, and W. Yu, “Single-Phase and Warm White-light-emitting Phosphors CaLa2−x−y(MoO4)4:xDy3+, yEu3+: Synthesis, Luminescence and Energy Transfer,” J. Lumin. 178, 61–67 (2016).
    [Crossref]
  11. K. Y. Yeh and W. R. Liu, “Luminescence Properties of NaCaGaSi2O7:RE, Li+ (RE = Ce3+, Eu3+ or Tb3+) Phosphors for UV Excitable White Light Emitting Diodes,” Mater. Res. Bull. 80, 127–134 (2016).
    [Crossref]
  12. C. H. Huang, T. W. Kuo, and T. M. Chen, “Thermally stable green Ba(3)Y(PO(4))3:Ce(3+),Tb(3+) and red Ca(3)Y(AlO)(3)(BO(3))4:Eu(3+) phosphors for white-light fluorescent lamps,” Opt. Express 19(S1), A1–A6 (2011).
    [Crossref] [PubMed]
  13. L. Qin, D. Wei, Y. Huang, S. I. Kim, Y. M. Yu, and H. J. Seo, “Efficient and Thermally Stable Red Luminescence from Nano-Sized Phosphor of Gd6MoO12:Eu3+,” J. Nanopart. Res. 15(9), 1940–1948 (2013).
    [Crossref]
  14. L. Qin, Y. Huang, T. Tsuboi, and H. J. Seo, “The Red-Emitting Phosphors of Eu3+-Activated MR2(MoO4)4 (M=Ba, Sr, Ca; R = La3+, Gd3+, Y3+) for Light Emitting Diodes,” Mater. Res. Bull. 47(12), 4498–4502 (2012).
    [Crossref]

2016 (3)

X. Y. Chen, Z. J. Zhang, F. F. Xu, S. Q. Shi, and J. T. Zhao, “Color-Tunable Carbon Dots/Y2WO6:Eu3+ Embedded Composite Bulk,” Opt. Mater. Express 6(2), 374–380 (2016).
[Crossref]

L. Han, G. Liu, X. Dong, J. Wang, and W. Yu, “Single-Phase and Warm White-light-emitting Phosphors CaLa2−x−y(MoO4)4:xDy3+, yEu3+: Synthesis, Luminescence and Energy Transfer,” J. Lumin. 178, 61–67 (2016).
[Crossref]

K. Y. Yeh and W. R. Liu, “Luminescence Properties of NaCaGaSi2O7:RE, Li+ (RE = Ce3+, Eu3+ or Tb3+) Phosphors for UV Excitable White Light Emitting Diodes,” Mater. Res. Bull. 80, 127–134 (2016).
[Crossref]

2013 (1)

L. Qin, D. Wei, Y. Huang, S. I. Kim, Y. M. Yu, and H. J. Seo, “Efficient and Thermally Stable Red Luminescence from Nano-Sized Phosphor of Gd6MoO12:Eu3+,” J. Nanopart. Res. 15(9), 1940–1948 (2013).
[Crossref]

2012 (2)

L. Qin, Y. Huang, T. Tsuboi, and H. J. Seo, “The Red-Emitting Phosphors of Eu3+-Activated MR2(MoO4)4 (M=Ba, Sr, Ca; R = La3+, Gd3+, Y3+) for Light Emitting Diodes,” Mater. Res. Bull. 47(12), 4498–4502 (2012).
[Crossref]

P. S. Dutta and A. Khanna, “Eu3+ Activated Molybdate and Tungstate Based Red Phosphors with Charge Transfer Band in Blue Region,” ECS J. Solid State Sci. Technol. 2(2), R3153–R3167 (2012).
[Crossref]

2011 (4)

C. H. Huang, T. W. Kuo, and T. M. Chen, “Thermally stable green Ba(3)Y(PO(4))3:Ce(3+),Tb(3+) and red Ca(3)Y(AlO)(3)(BO(3))4:Eu(3+) phosphors for white-light fluorescent lamps,” Opt. Express 19(S1), A1–A6 (2011).
[Crossref] [PubMed]

Y. L. Yang, X. M. Li, W. L. Feng, W. J. Yang, W. L. Li, and C. Y. Tao, “Effect of Surfactants on Morphology and Luminescent Properties of CaMoO4:Eu3+ Red Phosphors,” J. Alloys Compd. 509(3), 845–848 (2011).
[Crossref]

F. Du, Y. Nakai, T. Tsuboi, Y. Huang, and H. J. Seo, “Luminescence Properties and Site Occupations of Eu3+ Ions Doped in Double phosphates Ca9R(PO4)7 (R = Al, Lu),” J. Mater. Chem. 21(12), 4669–4678 (2011).
[Crossref]

C. H. Huang, T. W. Kuo, and T. M. Chen, “Thermally stable green Ba(3)Y(PO(4))3:Ce(3+),Tb(3+) and red Ca(3)Y(AlO)(3)(BO(3))4:Eu(3+) phosphors for white-light fluorescent lamps,” Opt. Express 19(S1), A1–A6 (2011).
[Crossref] [PubMed]

2010 (2)

P. Dorenbos, A. H. Krumpel, E. Kolk, P. Boutinaud, M. Bettinelli, and E. Cavalli, “Lanthanide Level Location in Transition Metal Complex Compounds,” Opt. Mater. 32(12), 1681–1685 (2010).
[Crossref]

E. Cavalli, P. Boutinaud, R. Mahiou, M. Bettinelli, and P. Dorenbos, “Luminescence Dynamics in Tb3+-doped CaWO4 and CaMoO4 Crystals,” Inorg. Chem. 49(11), 4916–4921 (2010).
[Crossref] [PubMed]

1991 (1)

A. R. Denton and N. W. Ashcroft, “Vegard’s Law,” Phys. Rev. A 43(6), 3161–3164 (1991).
[Crossref] [PubMed]

1982 (1)

J. B. Bourdet, R. Chevalier, J. P. Fournier, R. Kohlmuller, and J. Omaly, “A Structural Study of Cadmium Yttrium Molybdate CdY4Mo3O16,” Acta Crystallogr. B 38(9), 2371–2374 (1982).
[Crossref]

Ashcroft, N. W.

A. R. Denton and N. W. Ashcroft, “Vegard’s Law,” Phys. Rev. A 43(6), 3161–3164 (1991).
[Crossref] [PubMed]

Bettinelli, M.

P. Dorenbos, A. H. Krumpel, E. Kolk, P. Boutinaud, M. Bettinelli, and E. Cavalli, “Lanthanide Level Location in Transition Metal Complex Compounds,” Opt. Mater. 32(12), 1681–1685 (2010).
[Crossref]

E. Cavalli, P. Boutinaud, R. Mahiou, M. Bettinelli, and P. Dorenbos, “Luminescence Dynamics in Tb3+-doped CaWO4 and CaMoO4 Crystals,” Inorg. Chem. 49(11), 4916–4921 (2010).
[Crossref] [PubMed]

Bourdet, J. B.

J. B. Bourdet, R. Chevalier, J. P. Fournier, R. Kohlmuller, and J. Omaly, “A Structural Study of Cadmium Yttrium Molybdate CdY4Mo3O16,” Acta Crystallogr. B 38(9), 2371–2374 (1982).
[Crossref]

Boutinaud, P.

E. Cavalli, P. Boutinaud, R. Mahiou, M. Bettinelli, and P. Dorenbos, “Luminescence Dynamics in Tb3+-doped CaWO4 and CaMoO4 Crystals,” Inorg. Chem. 49(11), 4916–4921 (2010).
[Crossref] [PubMed]

P. Dorenbos, A. H. Krumpel, E. Kolk, P. Boutinaud, M. Bettinelli, and E. Cavalli, “Lanthanide Level Location in Transition Metal Complex Compounds,” Opt. Mater. 32(12), 1681–1685 (2010).
[Crossref]

Cavalli, E.

P. Dorenbos, A. H. Krumpel, E. Kolk, P. Boutinaud, M. Bettinelli, and E. Cavalli, “Lanthanide Level Location in Transition Metal Complex Compounds,” Opt. Mater. 32(12), 1681–1685 (2010).
[Crossref]

E. Cavalli, P. Boutinaud, R. Mahiou, M. Bettinelli, and P. Dorenbos, “Luminescence Dynamics in Tb3+-doped CaWO4 and CaMoO4 Crystals,” Inorg. Chem. 49(11), 4916–4921 (2010).
[Crossref] [PubMed]

Chen, T. M.

Chen, X. Y.

Chevalier, R.

J. B. Bourdet, R. Chevalier, J. P. Fournier, R. Kohlmuller, and J. Omaly, “A Structural Study of Cadmium Yttrium Molybdate CdY4Mo3O16,” Acta Crystallogr. B 38(9), 2371–2374 (1982).
[Crossref]

Denton, A. R.

A. R. Denton and N. W. Ashcroft, “Vegard’s Law,” Phys. Rev. A 43(6), 3161–3164 (1991).
[Crossref] [PubMed]

Dong, X.

L. Han, G. Liu, X. Dong, J. Wang, and W. Yu, “Single-Phase and Warm White-light-emitting Phosphors CaLa2−x−y(MoO4)4:xDy3+, yEu3+: Synthesis, Luminescence and Energy Transfer,” J. Lumin. 178, 61–67 (2016).
[Crossref]

Dorenbos, P.

E. Cavalli, P. Boutinaud, R. Mahiou, M. Bettinelli, and P. Dorenbos, “Luminescence Dynamics in Tb3+-doped CaWO4 and CaMoO4 Crystals,” Inorg. Chem. 49(11), 4916–4921 (2010).
[Crossref] [PubMed]

P. Dorenbos, A. H. Krumpel, E. Kolk, P. Boutinaud, M. Bettinelli, and E. Cavalli, “Lanthanide Level Location in Transition Metal Complex Compounds,” Opt. Mater. 32(12), 1681–1685 (2010).
[Crossref]

Du, F.

F. Du, Y. Nakai, T. Tsuboi, Y. Huang, and H. J. Seo, “Luminescence Properties and Site Occupations of Eu3+ Ions Doped in Double phosphates Ca9R(PO4)7 (R = Al, Lu),” J. Mater. Chem. 21(12), 4669–4678 (2011).
[Crossref]

Dutta, P. S.

P. S. Dutta and A. Khanna, “Eu3+ Activated Molybdate and Tungstate Based Red Phosphors with Charge Transfer Band in Blue Region,” ECS J. Solid State Sci. Technol. 2(2), R3153–R3167 (2012).
[Crossref]

Feng, W. L.

Y. L. Yang, X. M. Li, W. L. Feng, W. J. Yang, W. L. Li, and C. Y. Tao, “Effect of Surfactants on Morphology and Luminescent Properties of CaMoO4:Eu3+ Red Phosphors,” J. Alloys Compd. 509(3), 845–848 (2011).
[Crossref]

Fournier, J. P.

J. B. Bourdet, R. Chevalier, J. P. Fournier, R. Kohlmuller, and J. Omaly, “A Structural Study of Cadmium Yttrium Molybdate CdY4Mo3O16,” Acta Crystallogr. B 38(9), 2371–2374 (1982).
[Crossref]

Han, L.

L. Han, G. Liu, X. Dong, J. Wang, and W. Yu, “Single-Phase and Warm White-light-emitting Phosphors CaLa2−x−y(MoO4)4:xDy3+, yEu3+: Synthesis, Luminescence and Energy Transfer,” J. Lumin. 178, 61–67 (2016).
[Crossref]

Huang, C. H.

Huang, Y.

L. Qin, D. Wei, Y. Huang, S. I. Kim, Y. M. Yu, and H. J. Seo, “Efficient and Thermally Stable Red Luminescence from Nano-Sized Phosphor of Gd6MoO12:Eu3+,” J. Nanopart. Res. 15(9), 1940–1948 (2013).
[Crossref]

L. Qin, Y. Huang, T. Tsuboi, and H. J. Seo, “The Red-Emitting Phosphors of Eu3+-Activated MR2(MoO4)4 (M=Ba, Sr, Ca; R = La3+, Gd3+, Y3+) for Light Emitting Diodes,” Mater. Res. Bull. 47(12), 4498–4502 (2012).
[Crossref]

F. Du, Y. Nakai, T. Tsuboi, Y. Huang, and H. J. Seo, “Luminescence Properties and Site Occupations of Eu3+ Ions Doped in Double phosphates Ca9R(PO4)7 (R = Al, Lu),” J. Mater. Chem. 21(12), 4669–4678 (2011).
[Crossref]

Khanna, A.

P. S. Dutta and A. Khanna, “Eu3+ Activated Molybdate and Tungstate Based Red Phosphors with Charge Transfer Band in Blue Region,” ECS J. Solid State Sci. Technol. 2(2), R3153–R3167 (2012).
[Crossref]

Kim, S. I.

L. Qin, D. Wei, Y. Huang, S. I. Kim, Y. M. Yu, and H. J. Seo, “Efficient and Thermally Stable Red Luminescence from Nano-Sized Phosphor of Gd6MoO12:Eu3+,” J. Nanopart. Res. 15(9), 1940–1948 (2013).
[Crossref]

Kohlmuller, R.

J. B. Bourdet, R. Chevalier, J. P. Fournier, R. Kohlmuller, and J. Omaly, “A Structural Study of Cadmium Yttrium Molybdate CdY4Mo3O16,” Acta Crystallogr. B 38(9), 2371–2374 (1982).
[Crossref]

Kolk, E.

P. Dorenbos, A. H. Krumpel, E. Kolk, P. Boutinaud, M. Bettinelli, and E. Cavalli, “Lanthanide Level Location in Transition Metal Complex Compounds,” Opt. Mater. 32(12), 1681–1685 (2010).
[Crossref]

Krumpel, A. H.

P. Dorenbos, A. H. Krumpel, E. Kolk, P. Boutinaud, M. Bettinelli, and E. Cavalli, “Lanthanide Level Location in Transition Metal Complex Compounds,” Opt. Mater. 32(12), 1681–1685 (2010).
[Crossref]

Kuo, T. W.

Li, W. L.

Y. L. Yang, X. M. Li, W. L. Feng, W. J. Yang, W. L. Li, and C. Y. Tao, “Effect of Surfactants on Morphology and Luminescent Properties of CaMoO4:Eu3+ Red Phosphors,” J. Alloys Compd. 509(3), 845–848 (2011).
[Crossref]

Li, X. M.

Y. L. Yang, X. M. Li, W. L. Feng, W. J. Yang, W. L. Li, and C. Y. Tao, “Effect of Surfactants on Morphology and Luminescent Properties of CaMoO4:Eu3+ Red Phosphors,” J. Alloys Compd. 509(3), 845–848 (2011).
[Crossref]

Liu, G.

L. Han, G. Liu, X. Dong, J. Wang, and W. Yu, “Single-Phase and Warm White-light-emitting Phosphors CaLa2−x−y(MoO4)4:xDy3+, yEu3+: Synthesis, Luminescence and Energy Transfer,” J. Lumin. 178, 61–67 (2016).
[Crossref]

Liu, W. R.

K. Y. Yeh and W. R. Liu, “Luminescence Properties of NaCaGaSi2O7:RE, Li+ (RE = Ce3+, Eu3+ or Tb3+) Phosphors for UV Excitable White Light Emitting Diodes,” Mater. Res. Bull. 80, 127–134 (2016).
[Crossref]

Mahiou, R.

E. Cavalli, P. Boutinaud, R. Mahiou, M. Bettinelli, and P. Dorenbos, “Luminescence Dynamics in Tb3+-doped CaWO4 and CaMoO4 Crystals,” Inorg. Chem. 49(11), 4916–4921 (2010).
[Crossref] [PubMed]

Nakai, Y.

F. Du, Y. Nakai, T. Tsuboi, Y. Huang, and H. J. Seo, “Luminescence Properties and Site Occupations of Eu3+ Ions Doped in Double phosphates Ca9R(PO4)7 (R = Al, Lu),” J. Mater. Chem. 21(12), 4669–4678 (2011).
[Crossref]

Omaly, J.

J. B. Bourdet, R. Chevalier, J. P. Fournier, R. Kohlmuller, and J. Omaly, “A Structural Study of Cadmium Yttrium Molybdate CdY4Mo3O16,” Acta Crystallogr. B 38(9), 2371–2374 (1982).
[Crossref]

Qin, L.

L. Qin, D. Wei, Y. Huang, S. I. Kim, Y. M. Yu, and H. J. Seo, “Efficient and Thermally Stable Red Luminescence from Nano-Sized Phosphor of Gd6MoO12:Eu3+,” J. Nanopart. Res. 15(9), 1940–1948 (2013).
[Crossref]

L. Qin, Y. Huang, T. Tsuboi, and H. J. Seo, “The Red-Emitting Phosphors of Eu3+-Activated MR2(MoO4)4 (M=Ba, Sr, Ca; R = La3+, Gd3+, Y3+) for Light Emitting Diodes,” Mater. Res. Bull. 47(12), 4498–4502 (2012).
[Crossref]

Seo, H. J.

L. Qin, D. Wei, Y. Huang, S. I. Kim, Y. M. Yu, and H. J. Seo, “Efficient and Thermally Stable Red Luminescence from Nano-Sized Phosphor of Gd6MoO12:Eu3+,” J. Nanopart. Res. 15(9), 1940–1948 (2013).
[Crossref]

L. Qin, Y. Huang, T. Tsuboi, and H. J. Seo, “The Red-Emitting Phosphors of Eu3+-Activated MR2(MoO4)4 (M=Ba, Sr, Ca; R = La3+, Gd3+, Y3+) for Light Emitting Diodes,” Mater. Res. Bull. 47(12), 4498–4502 (2012).
[Crossref]

F. Du, Y. Nakai, T. Tsuboi, Y. Huang, and H. J. Seo, “Luminescence Properties and Site Occupations of Eu3+ Ions Doped in Double phosphates Ca9R(PO4)7 (R = Al, Lu),” J. Mater. Chem. 21(12), 4669–4678 (2011).
[Crossref]

Shi, S. Q.

Tao, C. Y.

Y. L. Yang, X. M. Li, W. L. Feng, W. J. Yang, W. L. Li, and C. Y. Tao, “Effect of Surfactants on Morphology and Luminescent Properties of CaMoO4:Eu3+ Red Phosphors,” J. Alloys Compd. 509(3), 845–848 (2011).
[Crossref]

Tsuboi, T.

L. Qin, Y. Huang, T. Tsuboi, and H. J. Seo, “The Red-Emitting Phosphors of Eu3+-Activated MR2(MoO4)4 (M=Ba, Sr, Ca; R = La3+, Gd3+, Y3+) for Light Emitting Diodes,” Mater. Res. Bull. 47(12), 4498–4502 (2012).
[Crossref]

F. Du, Y. Nakai, T. Tsuboi, Y. Huang, and H. J. Seo, “Luminescence Properties and Site Occupations of Eu3+ Ions Doped in Double phosphates Ca9R(PO4)7 (R = Al, Lu),” J. Mater. Chem. 21(12), 4669–4678 (2011).
[Crossref]

Wang, J.

L. Han, G. Liu, X. Dong, J. Wang, and W. Yu, “Single-Phase and Warm White-light-emitting Phosphors CaLa2−x−y(MoO4)4:xDy3+, yEu3+: Synthesis, Luminescence and Energy Transfer,” J. Lumin. 178, 61–67 (2016).
[Crossref]

Wei, D.

L. Qin, D. Wei, Y. Huang, S. I. Kim, Y. M. Yu, and H. J. Seo, “Efficient and Thermally Stable Red Luminescence from Nano-Sized Phosphor of Gd6MoO12:Eu3+,” J. Nanopart. Res. 15(9), 1940–1948 (2013).
[Crossref]

Xu, F. F.

Yang, W. J.

Y. L. Yang, X. M. Li, W. L. Feng, W. J. Yang, W. L. Li, and C. Y. Tao, “Effect of Surfactants on Morphology and Luminescent Properties of CaMoO4:Eu3+ Red Phosphors,” J. Alloys Compd. 509(3), 845–848 (2011).
[Crossref]

Yang, Y. L.

Y. L. Yang, X. M. Li, W. L. Feng, W. J. Yang, W. L. Li, and C. Y. Tao, “Effect of Surfactants on Morphology and Luminescent Properties of CaMoO4:Eu3+ Red Phosphors,” J. Alloys Compd. 509(3), 845–848 (2011).
[Crossref]

Yeh, K. Y.

K. Y. Yeh and W. R. Liu, “Luminescence Properties of NaCaGaSi2O7:RE, Li+ (RE = Ce3+, Eu3+ or Tb3+) Phosphors for UV Excitable White Light Emitting Diodes,” Mater. Res. Bull. 80, 127–134 (2016).
[Crossref]

Yu, W.

L. Han, G. Liu, X. Dong, J. Wang, and W. Yu, “Single-Phase and Warm White-light-emitting Phosphors CaLa2−x−y(MoO4)4:xDy3+, yEu3+: Synthesis, Luminescence and Energy Transfer,” J. Lumin. 178, 61–67 (2016).
[Crossref]

Yu, Y. M.

L. Qin, D. Wei, Y. Huang, S. I. Kim, Y. M. Yu, and H. J. Seo, “Efficient and Thermally Stable Red Luminescence from Nano-Sized Phosphor of Gd6MoO12:Eu3+,” J. Nanopart. Res. 15(9), 1940–1948 (2013).
[Crossref]

Zhang, Z. J.

Zhao, J. T.

Acta Crystallogr. B (1)

J. B. Bourdet, R. Chevalier, J. P. Fournier, R. Kohlmuller, and J. Omaly, “A Structural Study of Cadmium Yttrium Molybdate CdY4Mo3O16,” Acta Crystallogr. B 38(9), 2371–2374 (1982).
[Crossref]

ECS J. Solid State Sci. Technol. (1)

P. S. Dutta and A. Khanna, “Eu3+ Activated Molybdate and Tungstate Based Red Phosphors with Charge Transfer Band in Blue Region,” ECS J. Solid State Sci. Technol. 2(2), R3153–R3167 (2012).
[Crossref]

Inorg. Chem. (1)

E. Cavalli, P. Boutinaud, R. Mahiou, M. Bettinelli, and P. Dorenbos, “Luminescence Dynamics in Tb3+-doped CaWO4 and CaMoO4 Crystals,” Inorg. Chem. 49(11), 4916–4921 (2010).
[Crossref] [PubMed]

J. Alloys Compd. (1)

Y. L. Yang, X. M. Li, W. L. Feng, W. J. Yang, W. L. Li, and C. Y. Tao, “Effect of Surfactants on Morphology and Luminescent Properties of CaMoO4:Eu3+ Red Phosphors,” J. Alloys Compd. 509(3), 845–848 (2011).
[Crossref]

J. Lumin. (1)

L. Han, G. Liu, X. Dong, J. Wang, and W. Yu, “Single-Phase and Warm White-light-emitting Phosphors CaLa2−x−y(MoO4)4:xDy3+, yEu3+: Synthesis, Luminescence and Energy Transfer,” J. Lumin. 178, 61–67 (2016).
[Crossref]

J. Mater. Chem. (1)

F. Du, Y. Nakai, T. Tsuboi, Y. Huang, and H. J. Seo, “Luminescence Properties and Site Occupations of Eu3+ Ions Doped in Double phosphates Ca9R(PO4)7 (R = Al, Lu),” J. Mater. Chem. 21(12), 4669–4678 (2011).
[Crossref]

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L. Qin, D. Wei, Y. Huang, S. I. Kim, Y. M. Yu, and H. J. Seo, “Efficient and Thermally Stable Red Luminescence from Nano-Sized Phosphor of Gd6MoO12:Eu3+,” J. Nanopart. Res. 15(9), 1940–1948 (2013).
[Crossref]

Mater. Res. Bull. (2)

L. Qin, Y. Huang, T. Tsuboi, and H. J. Seo, “The Red-Emitting Phosphors of Eu3+-Activated MR2(MoO4)4 (M=Ba, Sr, Ca; R = La3+, Gd3+, Y3+) for Light Emitting Diodes,” Mater. Res. Bull. 47(12), 4498–4502 (2012).
[Crossref]

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Opt. Express (2)

Opt. Mater. (1)

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Opt. Mater. Express (1)

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Figures (6)

Fig. 1
Fig. 1 (a): the structural refinement of CdY4Mo3O16:0.5Eu3+. (b): The dependence of lattice a parameter and cell volume V on Eu3+ doping.
Fig. 2
Fig. 2 (a): the structural view of CdY4Mo3O16 framework along [001] direction; (b): the surrounding for two kinds of cations Y3+ ions.
Fig. 3
Fig. 3 the typical SEM pictures (a,b), TEM photo (c), HRTEM image (d) and the selected area electron diffraction pattern (e).
Fig. 4
Fig. 4 (a): The excitation spectra of CdY4-4xEu4xMo3O16 (x = 0.1, 0.5) (λem = 615 nm). Ecut-off is the wavelength at the intersection between x-axle and tangent line of excitation edge. (b): The dependence of Ecut-off on Eu3+ doping.
Fig. 5
Fig. 5 The representative emission spectra of CdY4-4xEu4xMo3O16 (x = 0.05, 0.5) under the UV excitation (395 nm). The inset is the dependence of the integrated emission intensities on the doping levels of 0.05-0.6.
Fig. 6
Fig. 6 temperature dependent spectra (a) and decay curves (b) of CdY4-4xEu4xMo3O16 (x = 0.5). Inset is the thermal quenching fit on the lifetimes.

Tables (1)

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Table 1 the PL QEs and CIE color coordinates of novel red-emitting

Equations (1)

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τ ( T ) = τ r 1 + [ τ r / τ n r ] exp ( Δ E / k T )

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