Abstract

The introduction of SiO2 affects the glass’s micro-structure and micro-defects as well as the corresponding optical and physical properties of the B2O3-containing multi-component phosphate glasses. The addition of SiO2 increases the transition temperature and causes shifts of the UV cut-off wavelength (λcut-off). The changes of λcut-off are closely related to the PO3-EC and PO4-EC defect centers that are associated with the Q2 tetrahedral in phosphate chains. The corresponding variations of Q2 units can also be found in the Raman, XPS, and 31P MAS-NMR spectra. With increasing the content of SiO2, the ratio of non-bridging oxygen (associated with Q2 units) is gradually decreased down to a critical level when SiO2/B2O3 ratio is 4/1.5, whereas the ratio of non-bridging oxygen increases when SiO2/B2O3 ratio is larger than 4/1.5, which suggests that the doping SiO2 can influence the concentration of PO3-EC and PO4-EC defects. Those results can be better obtained when the sample is exposed to gamma irradiation. As the SiO2 content increased gradually up to 4/1.5, the concentration of the PO3-EC defects declined, while the concentration of PO4-EC and the POHC defects increased when considering the irradiation dose, indicating that the addition of SiO2 can regulate the structure-related defects in phosphate based glasses.

© 2017 Optical Society of America under the terms of the OSA Open Access Publishing Agreement

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References

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  1. G. Galleani, S. H. Santagneli, Y. Messaddeq, M. de Oliveira, and H. Eckert, “Rare-earth doped fluoride phosphate glasses: structural foundations of their luminescence properties,” Phys. Chem. Chem. Phys. 19(32), 21612–21624 (2017).
    [PubMed]
  2. D. Möncke and D. Ehrt, “Irradiation-induced defects in different glasses demonstrated on a metaphosphate glass,” Glastech. Ber. Glass Sci. Technol. 74(7), 199–209 (2001).
  3. U. Natura and D. Ehrt, “Generation and healing behavior of radiation-induced optical absorption in fluoride phosphate glasses: the dependence on UV radiation sources and temperature,” Nucl. Instrum. Methods Phys. Res. B 174(1), 143–150 (2001).
  4. J. H. Campbell, J. S. Hayden, and A. Marker, “High-power solid-state lasers: a laser glass perspective,” Int. J. Appl. Glass Sci. 2(1), 3–29 (2011).
  5. D. Ehrt and W. Seeber, “Glass for high-performance optics and laser technology,” J. Non-Cryst. Solids 129(1–3), 19–30 (1991).
  6. P. Wang, M. Lu, F. Gao, H. Guo, Y. Xu, C. Hou, Z. Zhou, and B. Peng, “Luminescence in the fluoride-containing phosphate-based glasses: A possible origin of their high resistance to nanosecond pulse laser-induced damage,” Sci. Rep. 5, 8593 (2015).
    [PubMed]
  7. D. Ehrt, P. Ebeling, and U. Natura, “UV Transmission and radiation-induced defects in phosphate and fluoride-phosphate glasses,” J. Non-Cryst. Solids 263(1–4), 240–250 (2000).
  8. D. Ehrt, “UV-absorption and radiation effects in different glasses doped with iron and tin in the ppm range,” C. R. Chim. 5(11), 679–692 (2002).
  9. D. Möncke and D. Ehrt, “Radiation-induced defects in CoO- and NiO-doped fluoride, phosphate, silicate and borosilicate glasses,” Glass Sci. Technol. 75(5), 243–253 (2002).
  10. D. Möncke and D. Ehrt, “Irradiation induced defects in glasses resulting in the photoionization of polyvalent dopants,” Opt. Mater. 25(4), 425–437 (2004).
  11. D. Feng, Q. He, M. Lu, W. Li, W. Song, P. Wang, and B. Peng, “Investigations on the photoluminescence spectra and its defect-related nature for the ultraviolet transmitting fluoride-containing phosphate-based glasses,” J. Non-Cryst. Solids 425(6), 130–137 (2015).
  12. Q. He, P. Wang, M. Sun, M. Lu, and B. Peng, “Significant improvement of gamma irradiation resistance in CeO2 doped phosphate glass by co-doping with Sb2O3,” Opt. Mater. Express 7(3), 1113–1121 (2017).
  13. P. Wang, Q. He, M. Lu, W. Li, and B. Peng, “Evolutionary mechanism of the defects in the fluoride-containing phosphate based glasses induced by gamma radiation,” Sci. Rep. 6, 18926 (2016).
    [PubMed]
  14. T. Uesbeck, H. Eckert, R. Youngman, and B. Aitken, “The Structure of borophosphosilicate pure network former glasses studied by multinuclear NMR spectroscopy,” J. Phys. Chem. 121(3), 1838–1850 (2017).
  15. F. Wu, S. Li, Z. Chang, H. Liu, S. Huang, and Y. Yue, “Local structure characterization and thermal properties of P2O5-MgO-Na2O-Li2O glasses doped with SiO2,” J. Mol. Struct. 1118, 42–47 (2016).
  16. P. Rajbhandari, L. Montagne, and G. Tricot, “Doping of low Tg phosphate glass with Al2O3, B2O3 and SiO2: Part I-effect on glass property and stability,” Mater. Chem. Phys. 183, 542–550 (2016).
  17. Q. He, P. Wang, M. Lu, and B. Peng, “Investigations on the photoluminescence of the iron and cobalt doped fluoride-containing phosphate-based glasses and its defects-related nature,” J. Alloys Compd. 685, 153–158 (2016).
  18. R. K. Brow, “Review: the structure of simple phosphate glasses,” J. Non-Cryst. Solids 263(1), 1–28 (2000).
  19. E. C. Onyiriuka, “Zinc phosphate glass surfaces studied by XPS,” J. Non-Cryst. Solids 163(3), 268–273 (1993).
  20. R. J. Kirkpatrick and R. K. Brow, “Nuclear magnetic resonance investigation of the structures of phosphate and phosphate-containing glasses: a review,” Solid State Nucl. Magn. Reson. 5(1), 9–21 (1995).
    [PubMed]
  21. R. K. Brow, D. R. Tallant, S. T. Myers, and C. C. Phifer, “The short-range structure of zinc polyphosphate glass,” J. Appl. Phys. 54(7), 3743–3762 (1983).
  22. P. Ebeling, D. Ehrt, and M. Friedrich, “X-ray induced effects in phosphate glasses,” Opt. Mater. 20(2), 101–111 (2002).

2017 (3)

G. Galleani, S. H. Santagneli, Y. Messaddeq, M. de Oliveira, and H. Eckert, “Rare-earth doped fluoride phosphate glasses: structural foundations of their luminescence properties,” Phys. Chem. Chem. Phys. 19(32), 21612–21624 (2017).
[PubMed]

Q. He, P. Wang, M. Sun, M. Lu, and B. Peng, “Significant improvement of gamma irradiation resistance in CeO2 doped phosphate glass by co-doping with Sb2O3,” Opt. Mater. Express 7(3), 1113–1121 (2017).

T. Uesbeck, H. Eckert, R. Youngman, and B. Aitken, “The Structure of borophosphosilicate pure network former glasses studied by multinuclear NMR spectroscopy,” J. Phys. Chem. 121(3), 1838–1850 (2017).

2016 (4)

F. Wu, S. Li, Z. Chang, H. Liu, S. Huang, and Y. Yue, “Local structure characterization and thermal properties of P2O5-MgO-Na2O-Li2O glasses doped with SiO2,” J. Mol. Struct. 1118, 42–47 (2016).

P. Rajbhandari, L. Montagne, and G. Tricot, “Doping of low Tg phosphate glass with Al2O3, B2O3 and SiO2: Part I-effect on glass property and stability,” Mater. Chem. Phys. 183, 542–550 (2016).

Q. He, P. Wang, M. Lu, and B. Peng, “Investigations on the photoluminescence of the iron and cobalt doped fluoride-containing phosphate-based glasses and its defects-related nature,” J. Alloys Compd. 685, 153–158 (2016).

P. Wang, Q. He, M. Lu, W. Li, and B. Peng, “Evolutionary mechanism of the defects in the fluoride-containing phosphate based glasses induced by gamma radiation,” Sci. Rep. 6, 18926 (2016).
[PubMed]

2015 (2)

D. Feng, Q. He, M. Lu, W. Li, W. Song, P. Wang, and B. Peng, “Investigations on the photoluminescence spectra and its defect-related nature for the ultraviolet transmitting fluoride-containing phosphate-based glasses,” J. Non-Cryst. Solids 425(6), 130–137 (2015).

P. Wang, M. Lu, F. Gao, H. Guo, Y. Xu, C. Hou, Z. Zhou, and B. Peng, “Luminescence in the fluoride-containing phosphate-based glasses: A possible origin of their high resistance to nanosecond pulse laser-induced damage,” Sci. Rep. 5, 8593 (2015).
[PubMed]

2011 (1)

J. H. Campbell, J. S. Hayden, and A. Marker, “High-power solid-state lasers: a laser glass perspective,” Int. J. Appl. Glass Sci. 2(1), 3–29 (2011).

2004 (1)

D. Möncke and D. Ehrt, “Irradiation induced defects in glasses resulting in the photoionization of polyvalent dopants,” Opt. Mater. 25(4), 425–437 (2004).

2002 (3)

D. Ehrt, “UV-absorption and radiation effects in different glasses doped with iron and tin in the ppm range,” C. R. Chim. 5(11), 679–692 (2002).

D. Möncke and D. Ehrt, “Radiation-induced defects in CoO- and NiO-doped fluoride, phosphate, silicate and borosilicate glasses,” Glass Sci. Technol. 75(5), 243–253 (2002).

P. Ebeling, D. Ehrt, and M. Friedrich, “X-ray induced effects in phosphate glasses,” Opt. Mater. 20(2), 101–111 (2002).

2001 (2)

D. Möncke and D. Ehrt, “Irradiation-induced defects in different glasses demonstrated on a metaphosphate glass,” Glastech. Ber. Glass Sci. Technol. 74(7), 199–209 (2001).

U. Natura and D. Ehrt, “Generation and healing behavior of radiation-induced optical absorption in fluoride phosphate glasses: the dependence on UV radiation sources and temperature,” Nucl. Instrum. Methods Phys. Res. B 174(1), 143–150 (2001).

2000 (2)

D. Ehrt, P. Ebeling, and U. Natura, “UV Transmission and radiation-induced defects in phosphate and fluoride-phosphate glasses,” J. Non-Cryst. Solids 263(1–4), 240–250 (2000).

R. K. Brow, “Review: the structure of simple phosphate glasses,” J. Non-Cryst. Solids 263(1), 1–28 (2000).

1995 (1)

R. J. Kirkpatrick and R. K. Brow, “Nuclear magnetic resonance investigation of the structures of phosphate and phosphate-containing glasses: a review,” Solid State Nucl. Magn. Reson. 5(1), 9–21 (1995).
[PubMed]

1993 (1)

E. C. Onyiriuka, “Zinc phosphate glass surfaces studied by XPS,” J. Non-Cryst. Solids 163(3), 268–273 (1993).

1991 (1)

D. Ehrt and W. Seeber, “Glass for high-performance optics and laser technology,” J. Non-Cryst. Solids 129(1–3), 19–30 (1991).

1983 (1)

R. K. Brow, D. R. Tallant, S. T. Myers, and C. C. Phifer, “The short-range structure of zinc polyphosphate glass,” J. Appl. Phys. 54(7), 3743–3762 (1983).

Aitken, B.

T. Uesbeck, H. Eckert, R. Youngman, and B. Aitken, “The Structure of borophosphosilicate pure network former glasses studied by multinuclear NMR spectroscopy,” J. Phys. Chem. 121(3), 1838–1850 (2017).

Brow, R. K.

R. K. Brow, “Review: the structure of simple phosphate glasses,” J. Non-Cryst. Solids 263(1), 1–28 (2000).

R. J. Kirkpatrick and R. K. Brow, “Nuclear magnetic resonance investigation of the structures of phosphate and phosphate-containing glasses: a review,” Solid State Nucl. Magn. Reson. 5(1), 9–21 (1995).
[PubMed]

R. K. Brow, D. R. Tallant, S. T. Myers, and C. C. Phifer, “The short-range structure of zinc polyphosphate glass,” J. Appl. Phys. 54(7), 3743–3762 (1983).

Campbell, J. H.

J. H. Campbell, J. S. Hayden, and A. Marker, “High-power solid-state lasers: a laser glass perspective,” Int. J. Appl. Glass Sci. 2(1), 3–29 (2011).

Chang, Z.

F. Wu, S. Li, Z. Chang, H. Liu, S. Huang, and Y. Yue, “Local structure characterization and thermal properties of P2O5-MgO-Na2O-Li2O glasses doped with SiO2,” J. Mol. Struct. 1118, 42–47 (2016).

de Oliveira, M.

G. Galleani, S. H. Santagneli, Y. Messaddeq, M. de Oliveira, and H. Eckert, “Rare-earth doped fluoride phosphate glasses: structural foundations of their luminescence properties,” Phys. Chem. Chem. Phys. 19(32), 21612–21624 (2017).
[PubMed]

Ebeling, P.

P. Ebeling, D. Ehrt, and M. Friedrich, “X-ray induced effects in phosphate glasses,” Opt. Mater. 20(2), 101–111 (2002).

D. Ehrt, P. Ebeling, and U. Natura, “UV Transmission and radiation-induced defects in phosphate and fluoride-phosphate glasses,” J. Non-Cryst. Solids 263(1–4), 240–250 (2000).

Eckert, H.

G. Galleani, S. H. Santagneli, Y. Messaddeq, M. de Oliveira, and H. Eckert, “Rare-earth doped fluoride phosphate glasses: structural foundations of their luminescence properties,” Phys. Chem. Chem. Phys. 19(32), 21612–21624 (2017).
[PubMed]

T. Uesbeck, H. Eckert, R. Youngman, and B. Aitken, “The Structure of borophosphosilicate pure network former glasses studied by multinuclear NMR spectroscopy,” J. Phys. Chem. 121(3), 1838–1850 (2017).

Ehrt, D.

D. Möncke and D. Ehrt, “Irradiation induced defects in glasses resulting in the photoionization of polyvalent dopants,” Opt. Mater. 25(4), 425–437 (2004).

D. Ehrt, “UV-absorption and radiation effects in different glasses doped with iron and tin in the ppm range,” C. R. Chim. 5(11), 679–692 (2002).

D. Möncke and D. Ehrt, “Radiation-induced defects in CoO- and NiO-doped fluoride, phosphate, silicate and borosilicate glasses,” Glass Sci. Technol. 75(5), 243–253 (2002).

P. Ebeling, D. Ehrt, and M. Friedrich, “X-ray induced effects in phosphate glasses,” Opt. Mater. 20(2), 101–111 (2002).

D. Möncke and D. Ehrt, “Irradiation-induced defects in different glasses demonstrated on a metaphosphate glass,” Glastech. Ber. Glass Sci. Technol. 74(7), 199–209 (2001).

U. Natura and D. Ehrt, “Generation and healing behavior of radiation-induced optical absorption in fluoride phosphate glasses: the dependence on UV radiation sources and temperature,” Nucl. Instrum. Methods Phys. Res. B 174(1), 143–150 (2001).

D. Ehrt, P. Ebeling, and U. Natura, “UV Transmission and radiation-induced defects in phosphate and fluoride-phosphate glasses,” J. Non-Cryst. Solids 263(1–4), 240–250 (2000).

D. Ehrt and W. Seeber, “Glass for high-performance optics and laser technology,” J. Non-Cryst. Solids 129(1–3), 19–30 (1991).

Feng, D.

D. Feng, Q. He, M. Lu, W. Li, W. Song, P. Wang, and B. Peng, “Investigations on the photoluminescence spectra and its defect-related nature for the ultraviolet transmitting fluoride-containing phosphate-based glasses,” J. Non-Cryst. Solids 425(6), 130–137 (2015).

Friedrich, M.

P. Ebeling, D. Ehrt, and M. Friedrich, “X-ray induced effects in phosphate glasses,” Opt. Mater. 20(2), 101–111 (2002).

Galleani, G.

G. Galleani, S. H. Santagneli, Y. Messaddeq, M. de Oliveira, and H. Eckert, “Rare-earth doped fluoride phosphate glasses: structural foundations of their luminescence properties,” Phys. Chem. Chem. Phys. 19(32), 21612–21624 (2017).
[PubMed]

Gao, F.

P. Wang, M. Lu, F. Gao, H. Guo, Y. Xu, C. Hou, Z. Zhou, and B. Peng, “Luminescence in the fluoride-containing phosphate-based glasses: A possible origin of their high resistance to nanosecond pulse laser-induced damage,” Sci. Rep. 5, 8593 (2015).
[PubMed]

Guo, H.

P. Wang, M. Lu, F. Gao, H. Guo, Y. Xu, C. Hou, Z. Zhou, and B. Peng, “Luminescence in the fluoride-containing phosphate-based glasses: A possible origin of their high resistance to nanosecond pulse laser-induced damage,” Sci. Rep. 5, 8593 (2015).
[PubMed]

Hayden, J. S.

J. H. Campbell, J. S. Hayden, and A. Marker, “High-power solid-state lasers: a laser glass perspective,” Int. J. Appl. Glass Sci. 2(1), 3–29 (2011).

He, Q.

Q. He, P. Wang, M. Sun, M. Lu, and B. Peng, “Significant improvement of gamma irradiation resistance in CeO2 doped phosphate glass by co-doping with Sb2O3,” Opt. Mater. Express 7(3), 1113–1121 (2017).

Q. He, P. Wang, M. Lu, and B. Peng, “Investigations on the photoluminescence of the iron and cobalt doped fluoride-containing phosphate-based glasses and its defects-related nature,” J. Alloys Compd. 685, 153–158 (2016).

P. Wang, Q. He, M. Lu, W. Li, and B. Peng, “Evolutionary mechanism of the defects in the fluoride-containing phosphate based glasses induced by gamma radiation,” Sci. Rep. 6, 18926 (2016).
[PubMed]

D. Feng, Q. He, M. Lu, W. Li, W. Song, P. Wang, and B. Peng, “Investigations on the photoluminescence spectra and its defect-related nature for the ultraviolet transmitting fluoride-containing phosphate-based glasses,” J. Non-Cryst. Solids 425(6), 130–137 (2015).

Hou, C.

P. Wang, M. Lu, F. Gao, H. Guo, Y. Xu, C. Hou, Z. Zhou, and B. Peng, “Luminescence in the fluoride-containing phosphate-based glasses: A possible origin of their high resistance to nanosecond pulse laser-induced damage,” Sci. Rep. 5, 8593 (2015).
[PubMed]

Huang, S.

F. Wu, S. Li, Z. Chang, H. Liu, S. Huang, and Y. Yue, “Local structure characterization and thermal properties of P2O5-MgO-Na2O-Li2O glasses doped with SiO2,” J. Mol. Struct. 1118, 42–47 (2016).

Kirkpatrick, R. J.

R. J. Kirkpatrick and R. K. Brow, “Nuclear magnetic resonance investigation of the structures of phosphate and phosphate-containing glasses: a review,” Solid State Nucl. Magn. Reson. 5(1), 9–21 (1995).
[PubMed]

Li, S.

F. Wu, S. Li, Z. Chang, H. Liu, S. Huang, and Y. Yue, “Local structure characterization and thermal properties of P2O5-MgO-Na2O-Li2O glasses doped with SiO2,” J. Mol. Struct. 1118, 42–47 (2016).

Li, W.

P. Wang, Q. He, M. Lu, W. Li, and B. Peng, “Evolutionary mechanism of the defects in the fluoride-containing phosphate based glasses induced by gamma radiation,” Sci. Rep. 6, 18926 (2016).
[PubMed]

D. Feng, Q. He, M. Lu, W. Li, W. Song, P. Wang, and B. Peng, “Investigations on the photoluminescence spectra and its defect-related nature for the ultraviolet transmitting fluoride-containing phosphate-based glasses,” J. Non-Cryst. Solids 425(6), 130–137 (2015).

Liu, H.

F. Wu, S. Li, Z. Chang, H. Liu, S. Huang, and Y. Yue, “Local structure characterization and thermal properties of P2O5-MgO-Na2O-Li2O glasses doped with SiO2,” J. Mol. Struct. 1118, 42–47 (2016).

Lu, M.

Q. He, P. Wang, M. Sun, M. Lu, and B. Peng, “Significant improvement of gamma irradiation resistance in CeO2 doped phosphate glass by co-doping with Sb2O3,” Opt. Mater. Express 7(3), 1113–1121 (2017).

P. Wang, Q. He, M. Lu, W. Li, and B. Peng, “Evolutionary mechanism of the defects in the fluoride-containing phosphate based glasses induced by gamma radiation,” Sci. Rep. 6, 18926 (2016).
[PubMed]

Q. He, P. Wang, M. Lu, and B. Peng, “Investigations on the photoluminescence of the iron and cobalt doped fluoride-containing phosphate-based glasses and its defects-related nature,” J. Alloys Compd. 685, 153–158 (2016).

D. Feng, Q. He, M. Lu, W. Li, W. Song, P. Wang, and B. Peng, “Investigations on the photoluminescence spectra and its defect-related nature for the ultraviolet transmitting fluoride-containing phosphate-based glasses,” J. Non-Cryst. Solids 425(6), 130–137 (2015).

P. Wang, M. Lu, F. Gao, H. Guo, Y. Xu, C. Hou, Z. Zhou, and B. Peng, “Luminescence in the fluoride-containing phosphate-based glasses: A possible origin of their high resistance to nanosecond pulse laser-induced damage,” Sci. Rep. 5, 8593 (2015).
[PubMed]

Marker, A.

J. H. Campbell, J. S. Hayden, and A. Marker, “High-power solid-state lasers: a laser glass perspective,” Int. J. Appl. Glass Sci. 2(1), 3–29 (2011).

Messaddeq, Y.

G. Galleani, S. H. Santagneli, Y. Messaddeq, M. de Oliveira, and H. Eckert, “Rare-earth doped fluoride phosphate glasses: structural foundations of their luminescence properties,” Phys. Chem. Chem. Phys. 19(32), 21612–21624 (2017).
[PubMed]

Möncke, D.

D. Möncke and D. Ehrt, “Irradiation induced defects in glasses resulting in the photoionization of polyvalent dopants,” Opt. Mater. 25(4), 425–437 (2004).

D. Möncke and D. Ehrt, “Radiation-induced defects in CoO- and NiO-doped fluoride, phosphate, silicate and borosilicate glasses,” Glass Sci. Technol. 75(5), 243–253 (2002).

D. Möncke and D. Ehrt, “Irradiation-induced defects in different glasses demonstrated on a metaphosphate glass,” Glastech. Ber. Glass Sci. Technol. 74(7), 199–209 (2001).

Montagne, L.

P. Rajbhandari, L. Montagne, and G. Tricot, “Doping of low Tg phosphate glass with Al2O3, B2O3 and SiO2: Part I-effect on glass property and stability,” Mater. Chem. Phys. 183, 542–550 (2016).

Myers, S. T.

R. K. Brow, D. R. Tallant, S. T. Myers, and C. C. Phifer, “The short-range structure of zinc polyphosphate glass,” J. Appl. Phys. 54(7), 3743–3762 (1983).

Natura, U.

U. Natura and D. Ehrt, “Generation and healing behavior of radiation-induced optical absorption in fluoride phosphate glasses: the dependence on UV radiation sources and temperature,” Nucl. Instrum. Methods Phys. Res. B 174(1), 143–150 (2001).

D. Ehrt, P. Ebeling, and U. Natura, “UV Transmission and radiation-induced defects in phosphate and fluoride-phosphate glasses,” J. Non-Cryst. Solids 263(1–4), 240–250 (2000).

Onyiriuka, E. C.

E. C. Onyiriuka, “Zinc phosphate glass surfaces studied by XPS,” J. Non-Cryst. Solids 163(3), 268–273 (1993).

Peng, B.

Q. He, P. Wang, M. Sun, M. Lu, and B. Peng, “Significant improvement of gamma irradiation resistance in CeO2 doped phosphate glass by co-doping with Sb2O3,” Opt. Mater. Express 7(3), 1113–1121 (2017).

Q. He, P. Wang, M. Lu, and B. Peng, “Investigations on the photoluminescence of the iron and cobalt doped fluoride-containing phosphate-based glasses and its defects-related nature,” J. Alloys Compd. 685, 153–158 (2016).

P. Wang, Q. He, M. Lu, W. Li, and B. Peng, “Evolutionary mechanism of the defects in the fluoride-containing phosphate based glasses induced by gamma radiation,” Sci. Rep. 6, 18926 (2016).
[PubMed]

P. Wang, M. Lu, F. Gao, H. Guo, Y. Xu, C. Hou, Z. Zhou, and B. Peng, “Luminescence in the fluoride-containing phosphate-based glasses: A possible origin of their high resistance to nanosecond pulse laser-induced damage,” Sci. Rep. 5, 8593 (2015).
[PubMed]

D. Feng, Q. He, M. Lu, W. Li, W. Song, P. Wang, and B. Peng, “Investigations on the photoluminescence spectra and its defect-related nature for the ultraviolet transmitting fluoride-containing phosphate-based glasses,” J. Non-Cryst. Solids 425(6), 130–137 (2015).

Phifer, C. C.

R. K. Brow, D. R. Tallant, S. T. Myers, and C. C. Phifer, “The short-range structure of zinc polyphosphate glass,” J. Appl. Phys. 54(7), 3743–3762 (1983).

Rajbhandari, P.

P. Rajbhandari, L. Montagne, and G. Tricot, “Doping of low Tg phosphate glass with Al2O3, B2O3 and SiO2: Part I-effect on glass property and stability,” Mater. Chem. Phys. 183, 542–550 (2016).

Santagneli, S. H.

G. Galleani, S. H. Santagneli, Y. Messaddeq, M. de Oliveira, and H. Eckert, “Rare-earth doped fluoride phosphate glasses: structural foundations of their luminescence properties,” Phys. Chem. Chem. Phys. 19(32), 21612–21624 (2017).
[PubMed]

Seeber, W.

D. Ehrt and W. Seeber, “Glass for high-performance optics and laser technology,” J. Non-Cryst. Solids 129(1–3), 19–30 (1991).

Song, W.

D. Feng, Q. He, M. Lu, W. Li, W. Song, P. Wang, and B. Peng, “Investigations on the photoluminescence spectra and its defect-related nature for the ultraviolet transmitting fluoride-containing phosphate-based glasses,” J. Non-Cryst. Solids 425(6), 130–137 (2015).

Sun, M.

Tallant, D. R.

R. K. Brow, D. R. Tallant, S. T. Myers, and C. C. Phifer, “The short-range structure of zinc polyphosphate glass,” J. Appl. Phys. 54(7), 3743–3762 (1983).

Tricot, G.

P. Rajbhandari, L. Montagne, and G. Tricot, “Doping of low Tg phosphate glass with Al2O3, B2O3 and SiO2: Part I-effect on glass property and stability,” Mater. Chem. Phys. 183, 542–550 (2016).

Uesbeck, T.

T. Uesbeck, H. Eckert, R. Youngman, and B. Aitken, “The Structure of borophosphosilicate pure network former glasses studied by multinuclear NMR spectroscopy,” J. Phys. Chem. 121(3), 1838–1850 (2017).

Wang, P.

Q. He, P. Wang, M. Sun, M. Lu, and B. Peng, “Significant improvement of gamma irradiation resistance in CeO2 doped phosphate glass by co-doping with Sb2O3,” Opt. Mater. Express 7(3), 1113–1121 (2017).

Q. He, P. Wang, M. Lu, and B. Peng, “Investigations on the photoluminescence of the iron and cobalt doped fluoride-containing phosphate-based glasses and its defects-related nature,” J. Alloys Compd. 685, 153–158 (2016).

P. Wang, Q. He, M. Lu, W. Li, and B. Peng, “Evolutionary mechanism of the defects in the fluoride-containing phosphate based glasses induced by gamma radiation,” Sci. Rep. 6, 18926 (2016).
[PubMed]

D. Feng, Q. He, M. Lu, W. Li, W. Song, P. Wang, and B. Peng, “Investigations on the photoluminescence spectra and its defect-related nature for the ultraviolet transmitting fluoride-containing phosphate-based glasses,” J. Non-Cryst. Solids 425(6), 130–137 (2015).

P. Wang, M. Lu, F. Gao, H. Guo, Y. Xu, C. Hou, Z. Zhou, and B. Peng, “Luminescence in the fluoride-containing phosphate-based glasses: A possible origin of their high resistance to nanosecond pulse laser-induced damage,” Sci. Rep. 5, 8593 (2015).
[PubMed]

Wu, F.

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Xu, Y.

P. Wang, M. Lu, F. Gao, H. Guo, Y. Xu, C. Hou, Z. Zhou, and B. Peng, “Luminescence in the fluoride-containing phosphate-based glasses: A possible origin of their high resistance to nanosecond pulse laser-induced damage,” Sci. Rep. 5, 8593 (2015).
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T. Uesbeck, H. Eckert, R. Youngman, and B. Aitken, “The Structure of borophosphosilicate pure network former glasses studied by multinuclear NMR spectroscopy,” J. Phys. Chem. 121(3), 1838–1850 (2017).

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F. Wu, S. Li, Z. Chang, H. Liu, S. Huang, and Y. Yue, “Local structure characterization and thermal properties of P2O5-MgO-Na2O-Li2O glasses doped with SiO2,” J. Mol. Struct. 1118, 42–47 (2016).

Zhou, Z.

P. Wang, M. Lu, F. Gao, H. Guo, Y. Xu, C. Hou, Z. Zhou, and B. Peng, “Luminescence in the fluoride-containing phosphate-based glasses: A possible origin of their high resistance to nanosecond pulse laser-induced damage,” Sci. Rep. 5, 8593 (2015).
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T. Uesbeck, H. Eckert, R. Youngman, and B. Aitken, “The Structure of borophosphosilicate pure network former glasses studied by multinuclear NMR spectroscopy,” J. Phys. Chem. 121(3), 1838–1850 (2017).

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[PubMed]

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[PubMed]

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[PubMed]

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Figures (10)

Fig. 1
Fig. 1 Differential scanning calorimetry curves of SiO2-doped B2O3-containing phosphate based glasses with different SiO2:B2O3 ratios (1:1.5, 3:1.5, 4:1.5 and 6:1.5, respectively).
Fig. 2
Fig. 2 Internal transmission (without Fresnel reflection) spectra of SiO2-doped B2O3-containing phosphate based glasses with different SiO2:B2O3 ratios (1:1.5, 3:1.5, 4:1.5 and 6:1.5, respectively).
Fig. 3
Fig. 3 Absorption spectra of SiO2-doped B2O3-containing phosphate based glasses with different SiO2:B2O3 ratios (1:1.5, 3:1.5, 4:1.5 and 6:1.5, respectively) fitted with Gaussian components.
Fig. 4
Fig. 4 Raman spectra of SiO2-doped B2O3-containing phosphate based glasses with different SiO2:B2O3 ratios (1:1.5, 3:1.5, 4:1.5 and 6:1.5, respectively).
Fig. 5
Fig. 5 O1s XPS spectra of SiO2-doped B2O3-containing phosphate based glasses with different SiO2:B2O3 ratios (1:1.5, 3:1.5, 4:1.5 and 6:1.5, respectively) were fitted with a Voigt function. The detail fitting parameters are provided in Table 1.
Fig. 6
Fig. 6 31P MAS-NMR spectra and deconvolution model for SiO2-doped B2O3-containing phosphate based glasses with different SiO2:B2O3 ratios (1:1.5, 3:1.5, 4:1.5 and 6:1.5, respectively).
Fig. 7
Fig. 7 UV-visible transmission spectra and the corresponding photographs of SiO2-doped B2O3-containing phosphate based glasses with different SiO2:B2O3 ratios (1:1.5, 3:1.5, 4:1.5 and 6:1.5, respectively) at different total irradiation doses (0k, 20k, 100k, 250k, 500k, 1000k rad (Si)).
Fig. 8
Fig. 8 Absorption spectra of SiO2-doped B2O3-containing phosphate based glasses with different SiO2:B2O3 ratios (1:1.5, 3:1.5, 4:1.5 and 6:1.5, respectively) at different total irradiation doses (20k, 100k, 250k, 500k, 1000k rad(Si)).
Fig. 9
Fig. 9 Absorption peak’s area of several types of defects (POHC1, POHC2, OHC, PO4-EC, PO3-EC) in SiO2-doped B2O3-containing phosphate based glasses with different SiO2:B2O3 ratios (1:1.5, 3:1.5, 4:1.5 and 6:1.5, respectively) at different total irradiation doses (20k, 100k, 250k, 500k, 1000k rad(Si)).
Fig. 10
Fig. 10 Gamma irradiation induced change of relative concentration for several types of defects (POHC1, POHC2, OHC, PO4-EC, PO3-EC) in SiO2-doped B2O3-containing phosphate based glasses with different SiO2:B2O3 ratios (1:1.5, 3:1.5, 4:1.5 and 6:1.5, respectively) at different total irradiation doses (20k, 100k, 250k, 500k, 1000k rad(Si)).

Tables (2)

Tables Icon

Table 1 Parameters of the fitted BO and NBO peaks from the O1s XPS spectra of SiO2 doped B2O3-containing phosphate based glasses (The errors on the measurement are ± 0.3 eV for peak position and ± 2% for BO/(BO + NBO) ratio).

Tables Icon

Table 2 31P isotropic chemical shifts and relative area percentage of the individual Q(n) phosphate species, obtained from the deconvolution of the 31P MAS NMR spectra in Fig. 6 (The errors on the measurement are ± 0.1 ppm for δiso and ± 0.1% for ratio).

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